NEET Chemistry Important & Repeated Questions 2027

39 question types that recur across NEET Paper-1 shifts (2022–2025). NEET rarely repeats a question verbatim — but it reuses these templates every session. Master the pattern, not the numbers.

Some Basic Concepts in Chemistry
1. Stoichiometry (purity/neutralisation)
seen 3×202220232024
1 gram of sodium hydroxide was treated with 25 mL of 0.75 M HCl solution, the mass of sodium hydroxide left unreacted is equal to: (1) 200 mg (2) 750 mg (3) 250 mg (4) Zero mg
2. Number of atoms (mole concept)
seen 2×20242025
Among the following, choose the ones with equal number of atoms. A. 212 g of Na2CO3 (s) [molar mass = 106 g] B. 248 g of Na2O (s) [molar mass = 62 g] C. 240 g of NaOH (s) [molar mass = 40 g] D. 12 g of H2 (g) [molar mass = 2 g] E. 220 g of CO2 (g) [molar mass = 44 g]. Choose the correct answer from the options given below: (1) A, B, and C only (2) A, B, and D only (3) B, C, and D only (4) B, D, and E only
Atomic Structure
3. Bohr model calculations (H-like ions)
seen 4×202220242025
The ratio of the wavelengths of the light absorbed by a Hydrogen atom when it undergoes n = 2 -> n = 3 and n = 4 -> n = 6 transitions, respectively, is (1) 1/36 (2) 1/16 (3) 1/9 (4) 1/4
4. Quantum numbers significance/values
seen 2×20232024
Match List I with List II. List I (Quantum Number): A. ml B. ms C. l D. n List II (Information provided): I. shape of orbital II. size of orbital III. orientation of orbital IV. orientation of spin of electron Choose the correct answer from the options given below: (1) A-II, B-I, C-IV, D-III (2) A-I, B-III, C-II, D-IV (3) A-III, B-IV, C-I, D-II (4) A-III, B-IV, C-II, D-I
Chemical Bonding and Molecular Structure
5. MOT: bond order & magnetism
seen 3×202220232025
Given below are two statements: Statement I: A hypothetical diatomic molecule with bond order zero is quite stable. Statement II: As bond order increases, the bond length increases. In the light of the above statements, choose the most appropriate answer from the options given below: (1) Both Statement I and Statement II are true (2) Both Statement I and Statement II are false (3) Statement I is true but Statement II is false (4) Statement I is false but Statement II is true
6. Counting sigma/pi bonds
seen 2×20232024
Match List I with List II. List I (Molecule): A. ethane B. ethene C. carbon molecule, C2 D. ethyne List II (Number and types of bond/s between two carbon atoms): I. one σ-bond and two π-bonds II. two π-bonds III. one σ-bond IV. one σ-bond and one π-bond Choose the correct answer from the options given below: (1) A-III, B-IV, C-I, D-II (2) A-I, B-IV, C-II, D-III (3) A-IV, B-III, C-II, D-I (4) A-III, B-IV, C-II, D-I
7. VSEPR shapes & lone-pair repulsion
seen 2×20222024
Match List I with List II. List I (Compound): A. NH3 B. BrF5 C. XeF4 D. SF6 List II (Shape/geometry): I. Trigonal Pyramidal II. Square Planar III. Octahedral IV. Square Pyramidal Choose the correct answer from the options given below: (1) A-II, B-III, C-IV, D-I (2) A-I, B-IV, C-II, D-III (3) A-II, B-IV, C-III, D-I (4) A-III, B-IV, C-I, D-II
Chemical Thermodynamics
8. Work in expansion
seen 2×20222024
The work done during reversible isothermal expansion of one mole of hydrogen gas at 25°C from pressure of 20 atmosphere to 10 atmosphere is: (Given R = 2.0 cal K-1 mol-1) (1) 100 calories (2) 0 calorie (3) -413.14 calories (4) 413.14 calories
Solutions
9. Colligative properties
seen 2×20242025
Which of the following aqueous solution will exhibit highest boiling point? (1) 0.01M Urea (2) 0.01M KNO3 (3) 0.01M Na2SO4 (4) 0.015M C6H12O6
Equilibrium
10. Kp–Kc relation (Δn)
seen 2×20242025
For the reaction A(g) <=> 2B(g), the backward reaction rate constant is higher than the forward reaction rate constant by a factor of 2500, at 1000 K. [Given: R = 0.0831 L atm mol-1 K-1] Kp for the reaction at 1000 K is (1) 83.1 (2) 2.077 x 105 (3) 0.033 (4) 0.021
11. Kc & degree of dissociation numericals
seen 2×20222024
Consider the following reaction in a sealed vessel at equilibrium with concentrations of N2 = 3.0×10-3 M, O2 = 4.2×10-3 M and NO = 2.8×10-3 M. 2 NO_(g) ⇌ N2(g) + O2(g) If 0.1 mol L-1 of NO_(g) is taken in a closed vessel, what will be degree of dissociation (α) of NO_(g) at equilibrium? (1) 0.717 (2) 0.00889 (3) 0.0889 (4) 0.8889
Redox Reactions and Electrochemistry
12. Oxidation number/state
seen 3×202220242025
Consider the following compounds: KO2, H2O2 and H2SO4. The oxidation states of the underlined elements (O, O, S) in them are, respectively, (1) +1, -1, and +6 (2) +2, -2, and +6 (3) +1, -2, and +4 (4) +4, -4, and +6
13. Conductance / molar conductivity
seen 2×20232025
If the molar conductivity (Lambdam) of a 0.050 mol L-1 solution of a monobasic weak acid is 90 S cm2 mol-1, its extent (degree) of dissociation will be [Assume Lambda_+0 = 349.6 S cm2 mol-1 and Lambda_-0 = 50.4 S cm2 mol-1.] (1) 0.115 (2) 0.125 (3) 0.225 (4) 0.215
14. Faraday's laws
seen 2×2024
Match List I with List II. List I (Conversion): A. 1 mol of H2O to O2 B. 1 mol of MnO4^- to Mn2+ C. 1.5 mol of Ca from molten CaCl2 D. 1 mol FeO to Fe2O3 List II (Number of Faraday required): I. 3F II. 2F III. 1F IV. 5F Choose the correct answer from the options given below: (1) A-III, B-IV, C-II, D-I (2) A-II, B-IV, C-I, D-III (3) A-III, B-IV, C-I, D-II (4) A-II, B-III, C-I, D-IV
15. Redox feasibility from E°
seen 2×2022
At 298 K, the standard electrode potentials of Cu2+/Cu, Zn2+/Zn, Fe2+/Fe and Ag^+/Ag are 0.34 V, -0.76 V, -0.44 V and 0.80 V, respectively. On the basis of standard electrode potential, predict which of the following reaction can not occur? (1) 2CuSO4(aq) + 2Ag(s) -> 2Cu(s) + Ag2SO4(aq) (2) CuSO4(aq) + Zn(s) -> ZnSO4(aq) + Cu(s) (3) CuSO4(aq) + Fe(s) -> FeSO4(aq) + Cu(s) (4) FeSO4(aq) + Zn(s) -> ZnSO4(aq) + Fe(s)
Chemical Kinetics
16. First-order rate-law numericals
seen 3×20222025
If the half-life (t1/2) for a first order reaction is 1 minute, then the time required for 99.9% completion of the reaction is closest to (1) 2 minutes (2) 4 minutes (3) 5 minutes (4) 10 minutes
17. Arrhenius Ea (two temperatures)
seen 2×2024
Activation energy of any chemical reaction can be calculated if one knows the value of: (1) rate constant at two different temperatures. (2) rate constant at standard temperature. (3) probability of collision. (4) orientation of reactant molecules during collision.
Classification of Elements and Periodicity in Properties
18. Arrange by periodic trend
seen 2×2024
Arrange the following elements in increasing order of first ionization enthalpy: Li, Be, B, C, N Choose the correct answer from the options given below: (1) Li < Be < N < B < C (2) Li < Be < B < C < N (3) Li < B < Be < C < N (4) Li < Be < C < B < N
p- Block Elements
19. Group 16 hydride boiling points
seen 2×20222024
Given below are two statements: Statement I: The boiling point of hydrides of Group 16 elements follow the order H2O > H2Te > H2Se > H2S. Statement II: On the basis of molecular mass, H2O is expected to have lower boiling point than the other members of the group but due to the presence of extensive H-bonding in H2O, it has higher boiling point. In the light of the above statements, choose the correct answer from the options given below: (1) Statement I is false but Statement II is true. (2) Both Statement I and Statement II are true. (3) Both Statement I and Statement II are false. (4) Statement I is true but Statement II is false.
20. Carbon allotropes
seen 2×20222023
Match List-I with List-II: List-I: A. Coke, B. Diamond, C. Fullerene, D. Graphite List-II: I. Carbon atoms are sp3 hybridised. II. Used as a dry lubricant. III. Used as a reducing agent. IV. Cage like molecules Choose the correct answer from the options given below: (1) A-III, B-IV, C-I, D-II (2) A-II, B-IV, C-I, D-III (3) A-IV, B-I, C-II, D-III (4) A-III, B-I, C-IV, D-II
d- and f- Block Elements
21. Magnetic moment / unpaired electrons
seen 3×20242025
Given below are two statements: Statement I: Ferromagnetism is considered as an extreme form of paramagnetism. Statement II: The number of unpaired electrons in a Cr2+ ion (Z = 24) is the same as that of a Nd3+ ion (Z = 60). In the light of the above statements, choose the correct answer from the options given below: (1) Both Statement I and Statement II are true (2) Both Statement I and Statement II are false (3) Statement I is true but Statement II is false (4) Statement I is false but Statement II is true
Coordination Compounds
22. Magnetic behaviour of complexes
seen 2×20242025
Which of the following are paramagnetic? A. [NiCl4]2- B. Ni(CO)4 C. [Ni(CN)4]2- D. [Ni(H2O)6]2+ E. Ni(PPh3)4. Choose the correct answer from the options given below: (1) A and C only (2) B and E only (3) A and D only (4) A, D and E only
23. CFT wavelength/colour order
seen 2×20222025
The correct order of the wavelength of light absorbed by the following complexes is. A. [Co(NH3)6]3+ B. [Co(CN)6]3- C. [Cu(H2O)4]2+ D. [Ti(H2O)6]3+. Choose the correct answer from the options given below: (1) B < D < A < C (2) B < A < D < C (3) C < D < A < B (4) C < A < D < B
24. Homoleptic vs heteroleptic
seen 2×20232024
Given below are two statements: Statement I: [Co(NH3)6]3+ is a homoleptic complex whereas [Co(NH3)4Cl2]^+ is a heteroleptic complex. Statement II: Complex [Co(NH3)6]3+ has only one kind of ligands but [Co(NH3)4Cl2]^+ has more than one kind of ligands. In the light of the above statements, choose the correct answer from the options given below: (1) Statement I is false but Statement II is true. (2) Both Statement I and Statement II are true. (3) Both Statement I and Statement II are false. (4) Statement I is true but Statement II is false.
Purification and Characterisation of Organic Compounds
25. Purification techniques
seen 2×20242025
Match List I with List II. List I (Mixture): A. CHCl3 + C6H5NH2 B. Crude oil in petroleum industry C. Glycerol from spent-lye D. Aniline - water. List II (Method of Separation): I. Distillation under reduced pressure II. Steam distillation III. Fractional distillation IV. Simple distillation. Choose the correct answer from the options given below: (1) A-IV, B-III, C-I, D-II (2) A-IV, B-III, C-II, D-I (3) A-III, B-IV, C-I, D-II (4) A-III, B-IV, C-II, D-I
26. Lassaigne's test
seen 2×20232025
Which one of the following reactions does NOT belong to "Lassaigne's test"? (1) Na + C + N -heat-> NaCN (2) 2Na + S -heat-> Na2S (3) Na + X -heat-> NaX (4) 2CuO + C -heat-> 2Cu + CO2
Hydrocarbons
27. Alkene oxidative cleavage
seen 2×20222024
For the given reaction: (cyclohexyl)-CH=CH-(cyclohexyl) --KMnO4/H^+--> 'P' (major product). 'P' is: (the four options are structures shown in the figure) (1) cyclohexyl-CO-CO-cyclohexyl (diketone) (2) cyclohexanecarbaldehyde (cyclohexyl-CHO) (3) cyclohexanecarboxylic acid (cyclohexyl-COOH) (4) cyclohexyl-CH(OH)-CH(OH)-cyclohexyl (vicinal diol)
diagram for Alkene oxidative cleavage
28. Aromaticity / Hückel rule
seen 2×20222023
Consider the following compounds/species: i. naphthalene ii. cyclopentadienyl anion iii. cyclobutadiene dication (square four-membered ring) iv. cyclopropenyl anion (three-membered ring with negative charge) v. cyclopropenyl cation (three-membered ring with positive charge) vi. cyclooctatetraene vii. anthracene The number of compounds/species which obey Huckel's rule is ________. (1) 5 (2) 4 (3) 6 (4) 2
Organic Compounds Containing Halogens
29. SN1/SN2 reactivity
seen 2×20242025
Given below are two statements: one is labelled as Assertion (A) and the other is labelled as Reason (R). Assertion (A): 1-iodo compound undergoes SN2 reaction faster than the corresponding 1-chloro compound. Reason (R): Iodine is a better leaving group because of its large size. In the light of the above statements, choose the correct answer from the options given below: (1) Both A and R are true and R is the correct explanation of A (2) Both A and R are true but R is not the correct explanation of A (3) A is true but R is false (4) A is false but R is true
diagram for SN1/SN2 reactivity
Organic Compounds Containing Oxygen
30. Reagents for transformations
seen 3×20242025
Identify the suitable reagent for the following conversion. Methyl benzoate (Ph-CO-OCH3) -> benzaldehyde (Ph-CHO). (1) (i) LiAlH4, (ii) H^+/H2O (2) (i) AlH(iBu)2 (ii) H2O (3) (i) NaBH4, (ii) H^+/H2O (4) H2 / Pd-BaSO4
diagram for Reagents for transformations
31. Acidity order (phenols/acids)
seen 2×20222025
The correct order of decreasing acidity of the following aliphatic acids is (1) (CH3)3CCOOH > (CH3)2CHCOOH > CH3COOH > HCOOH (2) CH3COOH > (CH3)2CHCOOH > (CH3)3CCOOH > HCOOH (3) HCOOH > CH3COOH > (CH3)2CHCOOH > (CH3)3CCOOH (4) HCOOH > (CH3)3CCOOH > (CH3)2CHCOOH > CH3COOH
32. Grignard reactions
seen 2×20222025
The major product of the following reaction is: PhCO-CH2-CH2-CN (3-oxo-3-phenylpropanenitrile chain, i.e. an aryl ketone bearing a nitrile) treated with (i) CH3MgBr (excess) (ii) H3O^+. (1) tertiary alcohol from the ketone with CN retained: Ph-C(CH3)(OH)-CH2-CN (2) Ph-C(CH3)(OH)-CH2-CH2-CO-CH3 (alcohol from ketone + methyl ketone from nitrile) (3) diol: Ph-C(CH3)(OH)-CH2-C(OH)(CH3)2 (4) diketone: Ph-CO-CH2-CH2-CO-CH3
diagram for Grignard reactions
33. Aldehyde tests (Fehling/Tollens)
seen 2×20232024
Fehling's solution 'A' is: (1) aqueous sodium citrate (2) aqueous copper sulphate (3) alkaline copper sulphate (4) alkaline solution of sodium potassium tartrate (Rochelle's salt)
34. Lucas test
seen 2×20222024
Which one of the following alcohols reacts instantaneously with Lucas reagent? (1) (CH3)3C-OH (2) CH3-CH2-CH2-CH2OH (3) CH3-CH2-CH(OH)-CH3 (4) (CH3)2CH-CH2OH
35. Carbonyl nucleophilic addition products
seen 2×20222023
Complete the following reaction: Cyclohexanone (>C=O) --HCN--> [A] cyanohydrin (ring carbon bearing -OH and -CN) --conc. H2SO4, delta--> [C] [C] is ________. (1) cyclohexene ring bearing -COOH (an alpha,beta-unsaturated carboxylic acid; 1-cyclohexene carboxylic acid) (2) cyclohexane ring bearing -OH (3) cyclohexane ring bearing -COOH (4) cyclohexene ring bearing -CHO
Organic Compounds Containing Nitrogen
36. Amine synthesis sequence
seen 3×202220242025
Predict the major product 'P' in the following sequence of reactions - 1-methylcyclopentene reacting with (i) HBr, benzoyl peroxide (ii) KCN (iii) Na(Hg)/C2H5OH -> P (Major). (1) 2-methylcyclopentyl-CH2NH2 (2) 1-methylcyclopentyl-CH2NH2 (3) 2-methylcyclopentyl-NC (4) 1-methylcyclopentyl bearing NC and CH3
diagram for Amine synthesis sequence
37. Diazonium formation & stability
seen 2×20222025
Given below are two statements: Statement I: Benzenediazonium salt is prepared by the reaction of aniline with nitrous acid at 273-278 K. It decomposes easily in the dry state. Statement II: Insertion of iodine into the benzene ring is difficult and hence iodobenzene is prepared through the reaction of benzenediazonium salt with KI. In the light of the above statements, choose the most appropriate answer from the options given below: (1) Both Statement I and Statement II are correct (2) Both Statement I and Statement II are incorrect (3) Statement I is correct but Statement II is incorrect (4) Statement I is incorrect but Statement II is correct
Biomolecules
38. Monosaccharide properties & tests
seen 2×20242025
Sugar 'X': A. is found in honey. B. is a keto sugar. C. exists in alpha and beta - anomeric forms. D. is laevorotatory. 'X' is: (1) D-Glucose (2) D-Fructose (3) Maltose (4) Sucrose
Principles Related to Practical Chemistry
39. Cation analysis groups
seen 2×20242025
Match List I with List II. List I (Ion): A. Co2+ B. Mg2+ C. Pb2+ D. Al3+. List II (Group Number in Cation Analysis): I. Group-I II. Group-III III. Group-IV IV. Group-VI. Choose the correct answer from the options given below: (1) A-III, B-IV, C-II, D-I (2) A-III, B-IV, C-I, D-II (3) A-III, B-II, C-IV, D-I (4) A-III, B-II, C-I, D-IV
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